Khaldy, Adnan A. S. El and Shanab, Alaa M. Abu and Boni, Yannic (2017) Synthesis and Spectroscopic Characterization of Eight Chloro Cyclopentadienyl Titanium Bis (O, O-Dialkyl and Alkylene Dithiophosphate) Compounds. International Journal of Organic Chemistry, 07 (02). pp. 145-152. ISSN 2161-4687
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Abstract
A series of new complexes, CpTiCl[S2P(OR)2]2 (where R) Et, n-Pr, i-Pr, Bui, Ph) and CpTiCl [S2POGO]2 (where G) –CH2CMe2CH2-, -CMe2CMe2-) have been prepared by the drop wise addition of the appropriate O, O’-dialkyl or -alkylene dithiophosphoric acid to cyclopentadienyl titanium trichloride in 1:2 molar ratio and refluxed in benzene solution. The new compounds were characterized by molecular weight measurements elemental analyses and spectroscopic studies (1H, 13C, and 31P NMR, and in-frared). We suggest a distorted tetrahedron structure of these new complexes and the dithioligand behaves as bidentate ligand.
Item Type: | Article |
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Subjects: | Library Eprints > Chemical Science |
Depositing User: | Managing Editor |
Date Deposited: | 30 Mar 2023 06:04 |
Last Modified: | 24 Aug 2024 07:47 |
URI: | http://news.pacificarchive.com/id/eprint/1012 |